Nomenclature of Ionic Compounds

ionic compound:  a compound made out of the ions of a metal and a nonmetal

cation:  an ion with a positive charge, such as Na+ or Ca2+

anion:  an ion with a negative charge, such as Cl or S2−

stock system:  a system of naming compounds by naming the ions that they’re made of.  For example, a compound made of the ammonium ion and the chloride ion would be called “ammonium chloride”.  All ionic compounds are named using the stock system.


Naming the Cation

·      If the cation is a single element that has only one possible charge, the name of the cation is the name of the element.  For example, the K+ ion is simply named “potassium”, and the Ca2+ ion is simply named “calcium”.

·      If the element can have more than one possible charge, the name of the cation is the name of the element followed by a Roman numeral, indicating the charge, in paretheses.  For example, chromium can make cations with three different charges:

 

Formula of Cation

Name of Cation

Cr2+

chromium (II)

Cr3+

chromium (III)

Cr6+

chromium (VI)

 

·      If the cation is a polyatomic ion, its name is the name of the polyatomic ion.  For example, the NH4+ ion is named “ammonium”.


Naming the Anion

·      If an anion is a single element, the name of the ion is the name of the element with the ending changed to “ide”.  For example, the Cl ion is made from chlorine, so it is called “chloride”.  The O2− ion is made from oxygen, so it is called oxide.

·      If the anion is a polyatomic ion, its name is just the name of the polyatomic ion.  For example, the NO3 ion is named “nitrate”.